Kwonsnow
by Kwonsnow

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XAS

XAS vs observable

oxidation state of an element

interpretation

Nong, et al., Nature 2020, 587, 408, 10.1038/s41586-020-2908-2

  • operando XAS: hole concentration by quantifying the number of empty 5d states of Ir from Ir L2,3 edge
  • O 2p hole character, μ2-O (529 eV) and μ1-O oxyl (528.3 eV) from O K-edge XAS

Vacancy

EXAFS

EXAFS vs observable

The coordination environment of an element from bond distance

interpretation

XANES

XANES vs observable